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Taking the substrates 35 d and 35 e as examples, the LUMO of the substrates (and the SOMO of their radical anions) are sited on the allyl groups, thus allowing the selectivity of the observed reactions to be easily understood.
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Ac-electrogravimetry allows the selectivity of NO−3−PAA to be quantified.
Moreover an understanding of micromixing allows the selectivity of fast, multiple reactions to be better controlled.
Electrochemical models for photographic development allow the selectivity of the process to the rationalized.
The match between properties of the reactant and the solvent allows tuning the selectivity of the reaction.
The results obtained showed that the pH of the solution (pH 10), the electrode material (Pb) and potential of electrode (−2.0 V (MSE)) allowed to enhance the selectivity of lactic acid which reached 90% with a conversion yield of 92%.
This visualization shows the regions of selectivity between the drug-interaction contours and allows the comparison of the selectivity of a combination with the selectivity of individual drugs (Fig. 3, left panel).
Thus, the introduced modifications allowed us to enhance the selectivity of quinolines towards α7 nAChR and to get novel compounds with agonistic activity.
Selective deactivation of acid sites at the outer surface of the zeolite membrane (feed side of reactant) by the CCS method allowed us to increase the selectivity of the olefins by 10% as compared to the untreated membrane.
Optimisation of the reaction parameters (nature of the solvent system, concentration of the reagents, reaction temperature) allows to further increase the selectivity of the reaction under mild reaction conditions.
This will allow one to control the selectivity of the interaction with different nitroxides toward heightened sensitivity and selectivity of nanotube sensors at room temperature.
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