The developed approach allowed rationalization of experimental conditions to design direct electrochemical DNA biosensor with a detection limit of 10 pM.
Hence, by analyzing distances of receptors to their nearest neighbors in target space allows rationalization (and also prospective anticipation) of the performance of PCM models based on a set of related receptors.
Described OMC stands out as a highly versatile material, which can be used to replace carbon materials developed for specific purposes, allowing rationalization of carbon-based technologies aimed for energy conversion purposes.
One advantage of the approach described here is that it allows rationalization in terms of directly observable behaviours of mosquitoes and humans, as well as comparison of these patterns across diverse settings and timescales.
The above analysis allows rationalization of the experimental trends: whereas the fluorine inductive effect is responsible for the four-fold increase in H-bond acidity of 1 (compared to 9), any decrease in H-bond acidity is attributed to the unavailability of the OH group owing to an intramolecular F⋅⋅⋅HO interaction.
The retention equations obtained allow a rationalization of the interactions contributing to retention and separation in the HILIC systems considered.
New relationships, incorporating the activation energy for matrix diffusion (300 kJ mol−1) and the ultimate tensile strength values at the creep temperature, allow effective rationalization of the multi-batch stress rupture properties for Grade 92 steel (9Cr 0.5Mo 1.8W V Nb).
The gas phase and solvent dependent PM3 semiempirical modelling allowed further rationalization of experimental data pertinent to the suggested electrochemical redox mechanism and the reactivity of the intermediate species involved.
Systematic collection of hypotheses allows for rationalization of discussions about possible interpretation of data.
Highly specialized scanning transmission X-ray microscopy (STXM) has been proven to generate very detailed chemical composition maps; it provides information on local aluminum content and its coordination in dealuminated zeolites, allowing a rationalization of catalytic performance.
