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The large specific surface area can significantly enhance structural integrity by acting as mechanical buffer, effectively alleviating the volume changes generated during the lithiation/delithiation process.
However, few simple and effective method is explored for preparing iron oxides with high electrochemical performance via alleviating the volume change and agglomeration of active particles.
The polar MnO2 hollow spheres can not only provide enough inner space for alleviating the volume expansion for sulfur, but also effectively moderate the dissolution of polysulfides by synergistic effect of structural restriction and chemical adsorption.
This good performance can be ascribed to the 3D honeycomb carbon network in enhancing the electronic conductivity, shortening path lengths for electron transport, and alleviating the volume changes of electrode materials.
The abundant pores inside the FePx matrix can store sufficient electrolyte for fast ion transfer, as well as provide enough space for alleviating the volume change during charge/discharge process.
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Meanwhile, the free voids between neighboring Si nanocrystals alleviate the volume change of Si during cycling.
First, the approximately 3.5-nm pores can provide a space to alleviate the volume expansion during cycling.
Furthermore, the porous structures of MOFs-derived TiO2 effectively alleviate the volume change, shortens the diffusion path of Li+.
The porous structure and the RGO can effectively alleviate the volume changes resulted from charge discharge process.
The hierarchical flower-like microstructures can alleviate the volume change during charge/discharge cycles due to their porous nature.
The expanded interlayer space of p-Ti3C2 provides extra free space to alleviate the volume change of MoS2.
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