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These weak interactions combined, all the complexes displayed 3D structure.
Additional file 1: Figure S3 illustrates the geometric configurations for all the complexes, and Additional file 1: Table S1 tabulates the total energies for all the complexes.
At high decane content all the complexes have expanded coil conformations.
Low temperature magnetic study indicates small antiferromagnetic coupling for all the complexes.
Octahedral geometry is assigned to all the complexes based on the physical and spectral data.
TG-DTG studies reveal that all the complexes are thermally stable.
In DMF solutions at room temperature all the complexes display high-energy intraligand 1 fluorescence.
Solid state fluorescence study shows that all the complexes are luminescent at room temperature except complex 3.
The penetration is not the same for all the complexes, indicating the sample preparation has a notable influence in the availability of the drug to the PSi pore.
Table 3 shows the SAPT decomposition of the total interaction energies for all the complexes.
On coordination, the fluorescence quantum yields are slightly lowered for all the complexes (Table 1).
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