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The phrase "alienate them from" is correct and usable in written English.
It can be used when discussing the act of causing someone to feel isolated or estranged from a group or idea.
Example: "His constant criticism began to alienate them from the rest of the team."
Alternatives: "estrange them from" or "separate them from".
Exact(34)
The trauma tended to alienate them from their families.
Did the programme alienate them from the dominant culture of their company?
"Toxic politics and extreme polarisation in Turkey alienate them from political processes.
But other leaders said such labeling would alienate them from the denomination.
Does technology help kids connect with nature – through digital photography, or apps for identifying species – or alienate them from it?
Women like her didn't want to belong to anything that they thought would alienate them from men.
Similar(26)
And, also, that it has an effect on people: it alienates them from themselves and, eventually, kills or transforms them.
The dismal economy has sent many of the characters in Mr. Auster's novel reeling, alienating them from their families.
Until the end, he spent time at New Horizon's offices, oblivious to its users' sometimes rough teasing, anxious to understand what had alienated them from the mainstream.
Yet this mass movement never linked up with the Socialists, whose ideological anticlericalism alienated them from all wings of the Catholic movement.
For the Iraqi people, the crisis has further alienated them from their leaders, whom most regard as corrupt and out of touch with the lives of Iraqi citizens.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com