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The overall effect of concentration dependence of surface diffusivity is to enhance the rate of uptake during adsorption, and decrease it during desorption.
In contrast, at a high pH solution the percentage of dye removal will increase for cationic dye adsorption and decrease for anionic dye adsorption (Salleh et al. 2011).
The negative ΔS° reflected the affinity of the nanogels for Pb II) adsorption, and decrease in the randomness at solid solution interface during the removal of Pb II) ions onto AMPS nanogel surfaces, which is widely used in the most of the metal ions uptake process (Yangcheng et al. 2013).
However, the increase in the volume of small size pores (<5 nm) of Fouchana clay after adsorption and decrease in the volume of larger pores (5-14 nm) suggested a more extensive filling by dye in larger pores contrary to small pores and thus an increase in the number and volume of small pores.
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This leads to an increased adduct (PMT) adsorption and decreased product (PMBA) adsorption in the order V2O5<Li V2O5⪡K V2O5<Cs V2O5.
Motility tended to increase the adsorption rate, and decrease the desorption rate.
The enhanced PCE may be attributed to the increase of dye adsorption and the decrease of charge transfer resistance.
By increasing the molecular weight to 9 million, there was a sharp downtrend in injectivity due to the effect of adsorption, and the decrease in permeability, especially near KRA-4430 and BUR-4330, was significant at the late injection phase.
Accordingly, the surface area of the composite materials is a key parameter for BPA adsorption, and the decrease in the q e value of the composite materials is caused by a reduction in the surface area by Ti addition.
The association of Si, Ca and S on the surface is likely to increase passivation, and prevent Cr VI) adsorption and reduction, accounting for the decreased Cr VI) removal noted in the groundwater reacted NPs (compared to the model solution reacted NPs).
We also found that sodium cations present in natural brine are not inserted into the crystal lattice in the potential window explored, however they are adsorbed on the oxide surface blocking Li+ adsorption sites and decreasing the rate of Li+ exchange.
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