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The present study has focused on origins, which is interesting from the point of view of location policies involving zones that generate journeys (active accessibility), such as new residential developments, zones of denser growth or logistic urban micro-platforms.
Performances of the proposed model in reproducing the active accessibility to cinemas in the Naples metropolitan area (Italy) are compared to those of a traditional isochrone-based measure and a distance decay model.
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Improving pore interconnectivity, for example through swapping the p6 mm architecture of SBA-15 for the Ia3d of KIT-6 was subsequently explored as an alternative means to enhance in-pore active site accessibility (Scheme 1) for FFA esterification [82].
The effect of pore distribution of the FCC catalyst matrix on the active site accessibility of several catalysts has been tested tentatively in terms of bottoms conversion and strippable coke yield.
Changes in active site accessibility resulting from circular permutation led to increased catalytic rates for bulky fatty acid esters but did not overcome the steric hindrance or energetic limitations experienced by arylaliphatic esters.
A method for testing the active site accessibility of resid cracking catalysts has been developed on currently widely used MAT equipped with the unstripped hydrocarbon burned off in place, with an online measurement of the CO2 and H2O that are produced.
Notably, the catalytic activities of GST, CAT and GPX are very similar when these enzymes are packed into the nuclear shield or free in solution (Figure 4E), demonstrating that active site accessibility and functional flexibility are not impaired by the increased protein density.
This difference was explained by the length of three loops which modify the active center accessibility [ 50].
The first mechanism suggests a FXN-dependent increase in active site accessibility that allows DTT to intercept a catalytic intermediate and generate sulfide, which could drive nonenzymatic assembly of Fe S species.
Since no information on structural and functional asymmetry of the enzyme in solution is available in the literature, we investigated the active site accessibility by determining the cofactor fluorescence quenching of PMP- and PLP-GSAM forms.
Its regulation includes transcription, mRNA splicing, maturation and modifications of hTR and hTERT, transport and subcellular localisation of each component, assembly of the holoenzyme to an active ribonucleoprotein, accessibility and proper function on its telomeric substrates (Cong et al, 2002).
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