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The imidazole-based multi-carboxylate ligand demonstrates a strong coordination ability and versatile coordination modes.
The versatile coordination abilities of Zn II) allow for a wide variety of structures ranging from simple 1D infinite chains to robust, porous 3D frameworks with potential applications in sorption, separation and ion exchange.
The distinct structures of 1, 2, 3, 4 and 5 reveal that the anions and the versatile coordination modes of the ligand play an important role in the structures of the complexes.
In 1 5, the 2-PTP ligand adopts versatile coordination modes with various silver(I) salts to generate a series of supramolecular architectures.
The versatile coordination behavior of these diverse ligand systems is described.
These various architectures demonstrate the versatile coordination abilities of the imidazole-based multi-carboxylate ligand.
These various architectures demonstrate the versatile coordination abilities of the pyridine-substituted triazolyl benzoate ligand.
It is more remarkable that the building block bptc anion adopts versatile coordination modes in these complexes.
This work indicates that the building blocks oba and bpt can adopt versatile coordination modes depending on the nature of the metal centers.
Various coordination fashions and supramolecular networks are observed in complexes 1 3 due to the versatile coordination modes of the ligand and the cooperative effect from anions in the assemblies.
Four versatile coordination modes of carboxyl groups and Na O coordination bi-chains linked by novel μ-O bridges (μ2-O and μ3-O) were demonstrated in the structure.
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