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The phrase "a third layer" is correct and usable in written English.
It can be used when referring to an additional level or stratum in a context such as architecture, technology, or analysis.
Example: "In our analysis, we identified a third layer of complexity that had not been previously considered."
Alternatives: "an additional layer" or "a tertiary layer".
Exact(60)
She wore a third layer of makeup today".
Court records add a third layer to be interpreted.
Make a third layer of sauce and noodles.
Sometimes a third layer was added parallel to the first.
The military was putting a third layer on to a cement wall barricading the presidential palace.
Midway through sophomore year, undergraduates choose a concentration and get a third layer of support.
Hameed said a third layer of corruption had to be dealt with.
Add another single layer of salmon, another layer of potato and then a third layer of each.
High level commands are originated from a third layer called HLDU layer.
These have a third layer, consisting of a fine-grained dense mineral called garnet, at the bottom of the bed.
Fullerene was deposited as a third layer after initiating n-doping of the polymers.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com