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The phrase "a third group of" is correct and usable in written English.
It can be used when referring to an additional category or classification within a larger set of groups.
Example: "In our study, we identified a third group of participants who exhibited unique behavioral patterns."
Alternatives: "an additional group of" or "a separate group of".
Exact(60)
A third group of 130 people had both infections.
A third group of legislators received no letters.
A third group of selected genes affects brain function.
A third group of BTC's showed irregular shapes with several peaks.
A third group of 10 age-matched BALB/c mice served as an uninfected control group.
A third group of naïve, sedentary rats served as a negative control.
And a third group of students (a control group) didn't do anything at all.
A third group of records is a series of annual sermons from 1852-61.
Conodonts constitute a third group of index fossils important for Silurian correlation.
A third group of books I reread simply for the pleasure they give me.
A third group of iron-making techniques classed as smelting-reduction is still in its infancy.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com