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However, membranes produced by assisted self-assembly, exhibit a strong thickness dependence of their barrier properties.
Based on this model, one could understand that flat, uniform TMD layers on SiO2/Si substrates show a strong thickness dependence of the water contact angle (CA).
An increase in molar Si/Mg in the outer 30 nm may be just resolvable but this requires a strong thickness correction (the thickness changes by about 100 nm along the 130-nm rim profile, probably due to different sputtering yields of the Pt cover and the silicate).
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However, the wetting transparency model cannot explain the strong thickness dependence of CA in the case of non-uniform films.
A model accounting for the spatial variation of nanotube alignment relies on electron microscopy data and is consistent with the strong thickness dependence of the modulus data.
We note that the wetting transparency model also explains the strong thickness dependence of CA. C.-J. Shih et al. reported that 30% of the van der Waals interactions can be transmitted through the uniform ML graphene between water and the substrate [23].
A strong increase in thickness is observed after attachment of AuNP-citrate; this is not the case for AuNP-MDA.
As shown in Fig. 1, transmittance and reflectance spectra are altered after Ag deposition and the devices transform to the black states, indicating a strong influence of thickness and roughness on transmittance and reflectance.
A two stage degradation process has been observed, the first one presents a chemical modification of the polymer (decoloration of sample) and free carrier mobility reduction, the second one is characterized by a strong structural modification, thickness reduction, oxygen doping and further mobility reduction.
The fT values were a strong function of base thickness and doping.
The results reveal a strong nexus among membrane thickness, solution concentration and optimum length.
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