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The phrase "a rather more complex structure" is correct and usable in written English.
It can be used when comparing the complexity of different structures or systems, indicating that one is more complex than another.
Example: "The new design presents a rather more complex structure than the previous model, which may require additional resources for implementation."
Alternatives: "a significantly more intricate structure" or "a somewhat more complicated structure."
Exact(1)
Looking in detail at the repeated sequences "lITR-lICR-rICR-rITR-rE" in these elements allowed us to reveal a rather more complex structure.
Similar(59)
The statistical model incorporating substrate composition rather than substrate richness had a more complex structure, including the two 2-way interaction terms, species richness×substrate composition and substrate composition×time (Table 1).
"But it's a much bigger company with a much more complex structure.
A higher value with more contrast suggests a more complex structure.
A more complex structure is "Weather Prediction Instruments for Meteorologists," three disks of graduated size rods mounted one behind another.
Strontium atoms have two valence electrons and a more complex structure of electronic energy levels than alkali atoms.
In general, a family with more complex structure is newer.
Gardening as an activity, however, is rather more complex than the gardens in which it results.
But the ultimate solution is probably more significant, and rather more complex, than a simple ad ban.
However, the situation for mitochondrial disorders is rather more complex, for a number of reasons.
On a personal level for Pte Highgate, it is rather more complex.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com