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The phrase "a rare instance in" is correct and usable in written English.
It can be used to describe a unique or uncommon occurrence within a specific context or situation.
Example: "This is a rare instance in which all team members agreed on the proposed solution."
Alternatives: "an unusual case of" or "a unique example of".
Exact(56)
It was a rare instance in which officials had mentioned compensation in relation to the killings.
But it remains a rare instance in an era of the "no comment" brigade of hacked firms.
The deal is a rare instance in which Israel and Hezbollah have managed to reach an accord.
Arsenic was a rare instance in which there was some human data, especially for assessing bladder cancer rates.
Monday's attacks represented a rare instance in which the United Nations has used force against a conventional army.
It was a rare instance in this fierce political season that Republicans were not quick to respond.
The riots in Rosarno were a rare instance in which an entire city was engulfed by immigrant violence.
Similar(4)
He described a rare instance -- one in 5,000 cases -- in which the AIDS virus is dormant.
If Pell's insight into Mulkearns' thought process is correct, then it is a rare instance of someone in authority acting swiftly to protect someone in danger.
This occasioned a rare instance of criticism, in The Daily News, which scolded Mr. Schneiderman in September for letting his actions be guided "by political considerations".
This was a rare instance of conviction in a crime against Chinese immigrants.
More suggestions(2)
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com