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Alkyl, aryl, hetaryl, vinyl, and alkynyl ytterbium reagents participate in the reaction, greatly extending the utility of cyclobutenone rearrangements by providing a predictable means of introducing this isoprene unit in a regioselective manner.
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1, 2a It is readily introduced to a substrate as the electrophilic component in organolithium or Grignard addition reactions, for example, 1 a→ 2. Here, the differential reactivity of the C1 and C2 carbonyl groups in 1 a adds to its value as a synthon by providing a reliable and predictable means of achieving the ubiquitous head to tail connectivity of isoprene units.
The development of long coronary stents has provided a safe and predictable means of treating long coronary lesions, but this carries with it a higher risk of restenosis.
Deposition using an evaporating droplet is neither an efficient nor predictable means for achieving the deposition of large genomes.
This new law provides yet another arrow in the quiver of IP protections by creating a federal civil cause of action for trade secret theft, including the availability of a uniform, reliable and predictable means of protecting valuable trade secrets anywhere in the country.
Faulks achieves topicality by relatively predictable means, encompassing the Internet (YourPlace and Parallax stand in for Facebook and Second Life), the corruption of the banking system, fundamentalist fervors, reality television, and literary awards.
By contrast, Miller's "Centennial Collection" is a predictable assemblage, which means too many Ray Eberle vocals and an obligatory dose of wartime infantilism — "The Boogie Wooglie Piggy," with Miller's rather creepy vocal group, the Modernaires, harmonizing the oinks.
The lack of a predictable pattern also means that demand at any given location isn't overly artificial – it's people who are able to get there with almost no advance warning, basically.
The relationship of mean and standard deviation in the context of a t-test is not the same, for example, as in the context of the Central Limit Theorem, where the mean and standard deviation of populations have a predictable relationship to the means and standard deviations of the sampling distributions they can give rise to.
Similarly, measures of adiposity followed a predictable pattern, with the mean BMI, waist circumference, fat mass, and body fat percentage highest among the US participants and lowest among the Ghanaians.
Measures of adiposity followed a predictable pattern overall, with mean BMI, waist circumference, fat mass, and body fat percentage at their highest in US and lowest in Ghanaian subjects.
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CEO of Professional Science Editing for Scientists @ prosciediting.com