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The phrase "a more complex structure" is correct and usable in written English.
It can be used when discussing something that has multiple layers or components, indicating that it is not simple or straightforward.
Example: "The new software design features a more complex structure that allows for greater functionality and user customization."
Alternatives: "a more intricate framework" or "a more elaborate design".
Exact(60)
A more complex structure is "Weather Prediction Instruments for Meteorologists," three disks of graduated size rods mounted one behind another.
Yet as a site both sacred and defensive, the Kremlin was from its beginnings a more complex structure than those in the other cities.
In a region of the brain called the basal ganglia, known in people to be involved in language, the humanized mice grew nerve cells that had a more complex structure.
In the case of semiconductors, however, the electric double layer has a more complex structure inasmuch as the condenser plate at the electrode side of the double layer also becomes diffuse.
But as they were repeated — with long silences or delicate, pianissimo sounds (bells, a lightly bowed cello) between them, at first, then with more vigorous instrumental flourishes joining the sequence — the piece took on a more complex structure.
In a region of the brain called the basal ganglia, known in people to be involved in language, the humanized mice grew nerve cells that had a more complex structure and produced less dopamine, a chemical that transmits signals from one neuron to another.
Samuel P. Phelan and his two brothers considered these options, but they went for a more complex structure that allows them to have a say in the company and give their children control while leaving day-to-day operations in the hands of professional managers.
HIDiC has a more complex structure and slower dynamics than CDiC.
It is clear that the electrojet had a more complex structure than the simple uniform model gave.
The second example, however, displays a more complex structure, in which two different verbs participate in the Finite/Predicator structure.
Over 2 weeks, they watched as the cells formed a more complex structure that quickly came to resemble natural vocal cords.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com