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A method of derivation of linear driving force approximation for diffusion and reaction processes in porous catalysts based on Laplace Carson transform has been presented.
If a method of derivation is selected that optimizes the bond-valence sums for cations only, it is critical that these parameters be evaluated a posteriori to check that they also work well for anions.
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We have evaluated a photometric method of derivation of ionospheric conductivities based on simultaneous observations of a photometer (field of view = ~1.2°), a digital camera, and the EISCAT UHF radar (field of view = ~0.7°) operated at Tromsø, Norway (69.6°N, 19.2°E), for two nights on October 10 and 11, 2002.
A new method of derivation is introduced, the GRG (generalized reduced gradient) method, which leads to a mean weighted-RMSD of 0.128 v.u.
This result is probably due to the choice of method for the derivation of the bond-valence parameters, as this can greatly influence the quality of the fit; the use of a poor method of derivation that allows refinement of both R o and B can easily lead to a poorer fit than the method of fixing B, as will be shown later.
They suggested a new method of derivation that refines both R o and B using the following equation, obtained by rearrangement of the equation of Brown & Altermatt (1985 ▸) where c and are fitted constants.
We conclude that both (1) and (2) are not ideal, and we introduce a new method of derivation, the GRG (Generalized Reduced Gradient) method, that leads to better agreement with the valence-sum rule for both cation and anion bond-valence sums.
(5) The parameter R o/〈 R ij〉 is correlated with ion valence (R = 0.673) and ionization energy (R = 0.751), indicating that the potential correlation between R o and B does not adversely affect the derivation of bond-valence parameters provided an effective method of derivation is used.
Parameters derived by fixing a parameter are identified by their method of derivation (1, 2 or 3) in Table 4 ▸.
However, the minimization can be modified to become an integral part of the method of derivation of choice (next).
An alternate method of derivation may be accomplished by incorporating a mercury-binding site into RNA via a phosphorothioate in the RNA backbone.
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