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It was a very good performance, a grafting one – the Spanish are very hard to break down and defend very well so it was just a case of being patient.
A grafting method based on covalent coupling to aminosilane- and epoxysilane-functionalized surfaces was applied to obtain thin CMD layers.
For example, in a recent publication "click chemistry" was used to anchor an oligomer to silica particle wherein a grafting density of 0.34 chains/nm2[12].
The methine proton peak appearing at 3.65 ppm in 1H-NMR spectra could be assigned as a grafting site of GMA by the correlation spectra (H,H-COSY).
A grafting yield higher than 85% was obtained by using an amount of isocyanate terminated oligo(oxypropylene) of 0.2 mmol per gram of gelatin.
The fractions with a grafting density of 3.5 chains/nm as determined by TGA, displaying the highest colloidal stability, were selected for all further experiments.
A grafting density of ∼0.6 chains/nm was calculated from TGA for the grafting-to particles with 3.9 nm cores and ∼1.0 chains/nm for the grafting-to particles with 10.7 nm cores (see Table 1 ).
Similar(4)
A simple process to synthesize polyglycerol modified polysiloxane surfactants has been carried out applying a "grafting-to" approach.
P NIPAAm-co-CIPAAm s were covalently grafted onto amino-modified magnetite–silica comP NIPAAm-co-CIPAAm sng-to" method.
In order to accelerate foam degradation, this work examined a "grafting-from" method in which polyurethane (PU) chains were grown directly from functionalized TiO2 nanoparticle surfaces.
Therefore, a grafting-to approach onto reactive groups along the polymer backbone was developed as an alternate strategy.
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