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The expression [1 – R tmix)] represents the fraction of chains exchanged as a function of mix time, and c0[1 – R tmix)] represents the concentration of mixed chains, in which c0 was the total constant polymer concentration.
A linear model was formed as a function of mix tiles fraction and the analysis of ANOVA suggest that the linear term used for this model is significant.
Figure 4b shows the concentration of exchanged chains as a function of mix time by assuming that the chain exchange process followed a zero-order rate expression with respect to polymer concentration and mix time.
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Second, they reveal a crossover between different morphological regimes as a function of mixing rate.
The MS increases monotonically as a function of mixing speed, with a change of slope corresponding to the transition from laminar to turbulent mixing regimes.
The PBA equilibrium parameter and the gas-to-solid mass transfer coefficient during reaction are estimated as a function of mixing intensity, oxygen partial pressure, and catalyst concentration.
In other studies, the MS has been measured as a function of mixing speed in numerous sized reactors from 10 to 1000 l, and provides consistent and reproducible measurements.
The former was measured using fluorescence changes of aqueous insulin/silicone dispersions, while the latter examined changes in turbidity as a function of mixing and silicone oil type; the results were confirmed at two different insulin concentrations and agitation speeds.
In this study a high-pressure sapphire visual autoclave apparatus was used to measure the size of crude oil droplets that were saturated with gas and dispersed in an aqueous phase as a function of mixing speed.
Thin sections of cured nanocomposites obtained by a cryostate-microtome were analyzed by TEM while small and ultra small angle X-ray scattering (U/SAXS) was used to determine nanocomposite structure: filler primary particle, aggregate (chemically or sinter-bonded particles) and agglomerate (physically-bonded particles) size as a function of mixing duration and filler concentration.
In this paper, blends of Nylon 6,6 with the liquid crystal polymer Vectra A950 are considered; specifically we focused our attention on Nylon 6,6 modifications by interchange reactions that can occur in the melt, as a function of mixing conditions and blend compositions.
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