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Finance Minister Helmut Schmidt, an opponent of the planning concepts, prevented a direct coordination of financial and task planning between the Finance Ministry and the Chancellery and, not least as a result of rivalries in the cabinet, Ehmke had to switch to the Technology Ministry in 1972 [47 Jäger, p 33; 95 Süß, pp 369 77; 85 Schatz].
Intriguingly, members of the Mcm complex are also phosphorylated by ATM/ATR, suggesting a direct coordination of their activity in the presence of DNA lesions activating the checkpoint (Cortez et al, 2004; Yoo et al, 2004b).
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These observations further support a mechanism that proceeds via direct coordination of sulfur to the metal center and where the relative positioning of the thiol moiety plays a critical role in determining, whether oxygenation occurs at the iron or sulfur.
A visible transition of the cysteine-coordinated Fe(III -CDO further III -CDOd direct coordination ofurtherindicatede metal cofactor [50].
The 3.0 Å resolution structure of the XDH-alloxanthine complex shows direct coordination of alloxanthine to the molybdenum via a nitrogen atom.
Ion pairs which contain a bounded trimethylaluminium molecule give rise to active species, whereas direct coordination of the MAO cage to the catalyst leads to dormant species for polymerisation.
In fact, direct coordination of the ε-amino group with a transition metal is rare.
The loss of the direct coordination of the bromine neighbors to the Mn central atom was also evidenced by EXAFS spectra, e.g. loss of Br backscattering in the Mn K-EXAFS spectra and the Mn-backscattering in the Br K-edge spectra.
Different strategies for labelling proteins are presented including the direct coordination of amino acid functional groups to the metal ion, metal complexes where one or more of the ligands coordinated to the metal ion contain reactive functional groups for conjugation to peptides or proteins, and metal complexes designed for site selective bioorthogonal conjugation.
Furthermore, the close proximity of MMPs and integrins at these sites enables direct coordination of migration and invasion processes.
We observe partial direct coordination of the side chain carboxylate in D139E with Fe(II); thus, the occupancy of water 2 is reduced similarly.
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