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The chemical bond between the metal and the ligands and the origins of orbital splitting are ascribed not only to electrostatic forces but also to a small degree of overlap of metal and ligand orbitals and a delocalization of metal and ligand electrons.
Specifically, NeoA treatment led to a delocalization of the focal adhesion scaffolding proteins paxillin and vinculin as well as a decrease in the phosphorylated form of focal adhesion kinase from characteristic longitudinal streaks at the cell-substratum interface in MDA-MB-231 tumor cells (Figure 2A).
Although the RBR was dispensable for the interaction with PRC1, its disruption resulted not only in a delocalization of SCML2A from chromatin, but also in decreased PRC1 occupancy at several target genes.
In patients with SS, the salivary and lacrimal glands exhibit a marked reduction in AQP expression in the plasma membrane [ 39], as well as a delocalization of AQP5 to the basal membrane [ 40].
It was recently reported that, in CdSe/CdS colloidal QDs, which have a quasi-type-II band alignment corresponding to a delocalization of the electron wave function in the barrier material, a ΔBD as low as 250 μeV is achieved on thick-shell samples.
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The domination of a particular component indicates a substantial delocalization of charges in that direction.
This assumption of only a partial delocalization of π-electrons, rather than a complete one, is confirmed by the decrease of steady-state anisotropy at longer emission wavelengths (Fig. 5).
The fused bicyclic topology of radical anion [ 2].− obviously prevents the highly twisted arrangement of Ge Ge bond, which is needed for a complete separation and allows for a certain delocalization of the additional electron across both germanium atoms, as indicated by the calculated spin density for radical anion [ 2].−.
The reason for this high acidity is probably a strong delocalization of the negative charge over three cyano groups around CH bond.
For environmental remediation and clean energy applications, niobates, such as (Na, K NbO3 [8], BiNbO4 [9], LiNbO3 [10], and LiNb3O8 [11], have been deeply investigated, owing to their special distorted [NbO6] octahedral structures which favor a possible delocalization of charge carriers [12].
In the first stage of the charging process we assume that the originally twisted segments become more planar, enabling a better delocalization of charges along the chain (intramolecular stabilization).
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