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In the oxalate structure, the differences between these groups are even greater 1.339 5) Å and 1.280 5) Å, which disagree with a delocalisation concept and the data found in the literature (1.302-1.312 Å).
It was the same for LdARL-1/Q74L-GFP (GTP), which was different from mammals, where ARL-1/Q71L (GTP) led to an expansion of the Golgi and a delocalisation of ARF-1 [18].
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The treatment of J16 cells with H2O2 also provoked a dose-dependent delocalisation of cathepsin B from the lysosomal compartments to cytosol (see Fig. 3B).
Careful examination of the X-ray single-crystal structures shows that the phenate anion develops a C=O double bond and that the C C bond lengths in the ring suggest a Meissenheimer-like delocalisation.
Also, α- benzo[b]furan-2-yl -α-hydroxy malonic acid 22 was prepared to compare with 8 a, with the expectation being that extending the aromatic system from a furyl ring to a benzofuryl system would increase delocalisation of negative charge, resulting from decarboxylation, consequently resulting in a greater rate of reaction.
This delocalisation creates a potentially untenable situation for humanitarian agencies, as their security management options have become severely limited.
Our data indicate that charge delocalisation is a suitable strategy to engineer more potent analogues of MP that differentially target intracellular proteins.
Probably, photo-generation of ROS represents a signal in the delocalisation and insertion of Bax on the OMM.
For the lowest-energy conformer of each +HHNR1R2NCOO− and HNR1R2NCOO− derivative, Table 3 provides the calculated N COO− bond length (rN C ), rC1 O1/ rC1–O2 and ESP partial negative charges on both oxygen atoms as a measure of charge delocalisation.
France's new Socialist government has appointed a minister, Arnaud Montebourg, to resist "delocalisation".
The band-gap of poly(1) (1.6 1.7 eV) was found to be significantly lower than that of polypyrrole (2.85 eV) and polythiophene (2.3 eV) as a consequence of increased electron delocalisation in the system.
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