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This results in a decrease of the applied potential and the consequent avoidance of many electrochemical interferences.
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A voltammogram is a plot of the current as a function of the applied potential.
The water content of anodic layer should increase according to the pH and layer thickness and decrease on increasing the applied potential.
The applied potential corresponds to the potential on the plateau of a voltammetric wave of the assayed material.
The relationship between the applied potentials and activation parameters was investigated and was shown that Ea and ΔG≠ decreased linearly by increasing negative applied potential.
From the feature of the current transients obtained, the n, pit growth rate parameter b and induction time tm after which the growth of stable pits occurs were found to decrease with increasing applied potential in the applied potential range relatively lower than pitting potential.
In all cases the resistance of both inner and outer layer decrease with increasing applied potential.
The induction time, after which the growth of stable pits occurs, decreased with increasing applied potential and [SCN−].
Transition time tT at which current decay transients intersect for given applied potentials decreased with increasing applied potential.
Furthermore, the desorption time obtained from a potentiometric response to the removal of BTA from the electrolyte increases with increasing BTA concentration or decreasing applied potential.
The potentiostatic current/time transients show that the incubation time decreases with increasing the applied anodic potential and the Cl− ion concentration and the pitting corrosion can be described in terms of instantaneous three-dimensional growth under diffusion control.
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