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As the motion of the carriers (or excitons) becomes restrained, their energy spectra change, moving the permitted energy levels towards higher energies as a consequence of confinement.
Room temperature SAXS and wide-angle X-ray diffraction (WAXS) measurements indicate that two lamellar populations develop: edge-on lamellae are proposed to appear close to the interphases while flat-on lamellae, arising as a consequence of confinement, should be preferentially located in the layers core.
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Extraordinary properties of nanostructures are mainly a consequence of quantum confinement effects.
The PL peak shifts to longer wavelength with increasing CdSe sizes as a consequence of quantum confinement.
The absorption maximum and the PL peak shift to red wavelengths with increasing NC size as a consequence of quantum confinement.
Likewise, phase transformation kinetics would seem to be altered due to restrictions of the molecular movement as a consequence of the confinement inside the porous material.
Results suggest that flat-on lamellae arise as a consequence of spatial confinement and edge-on lamellae could be generated due to the interactions with the PC interface.
It is a well-established fact that as a consequence of quantum confinement of photogenerated electron-hole pair, the UV-vis absorption spectra of semiconductor quantum dots is size dependent [23].
These small values are a consequence of the strong confinement.
That is a consequence of the strong confinement of the states in the kink potential.
The uptake of PMo12 on carbon supports follows a clear correlation with the micropore volume, which implies that PMo12 is mainly adsorbed in microporosity as a consequence of a greater confinement in this kind of pores instead of mesopores.
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