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The phrase "a chief of a" is grammatically correct and can be used in written English.
It can be used when referring to a leader or head of a specific group, organization, or department.
Example: "She was appointed as a chief of a new initiative aimed at improving community health."
Alternatives: "a leader of a" or "the head of a".
Exact(4)
They care for a chief of a tribe here, a mullah there, a religious man here, a militiaman here, head of a party there".
The co-chairmen of that commission -- Erskine B. Bowles, who was a chief of a staff to President Bill Clinton, and former Senator Alan K. Simpson -- were in the audience Wednesday, along with Mr. Biden.
A chief of a lineage or longhouse, for example, would amass as much food and material goods as he could in order to lay on a feast and give presents lavishly in hopes that the guest lineage would be unable to reciprocate on the same scale.
A chief of a clinic must be part of the team, to put in his or her contribution.
Similar(55)
To Westerners, it seemed a curious tribute: a gesture of respect from a self-proclaimed democratic reformer to a chief of an infamous machine of repression.
After explaining what democracy was, a pamphlet outlined why Deposing a chief-of-state is a vital act.
There was a chief of staff and a deputy chief of staff; a superintendent of police and a deputy superintendent.
Sebetwane was a chief of the Patsa, a subgroup of the Sotho (Basuto).
Her father is a chief of security at Imperial Security, a security guard firm in Memphis.
Walmart recently named a chief of e-commerce logistics, a new job.
This is largely because the selection of a chief of staff signals the direction of a presidency.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com