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GHs representing glycosidases and transglycosidases are responsible for the hydrolysis of the glycosidic bonds linking two or more carbohydrates or a carbohydrate and a non-carbohydrate moiety accounting for about 6.5% of the total sequences.
Cellulosic biomass is the most abundant renewable resource on earth, whose natural degradation represents an important part of the carbon cycle within the biosphere [ 1]. β-Glucosidase (EC 3.2.1.21) is a glucosidase enzyme that acts upon β 1 4 bonds linking two glucose or glucose-substituted molecules.
It is a head-to-tail cyclized 35-residue peptide with three thioether bonds linking three cysteine residues to the α-carbons of two phenylalanines and one threonine.
This graph is generated by replacing the bond flux linking two ions by a single link representing the presence of a bond.
Sixteen interaction modes involve a single hydrogen bond linking the two units.
As a structural building block, a disulfide bond covalently links two cysteine residues in the same protein or in different proteins to strengthen the correct conformation of a protein or protein complex, thereby improving stability.
A radical mechanism for repair of SP by SPL was proposed by Mehl and Begley in 1999, where they proposed that an H-atom abstraction from C6 of SP could promote a radical-mediated β-scission to cleave the C C bond linking the two thymines.
While numerous low-abundance fragments can be detected in each case, the two most prominent fragments consistently correspond to the dissociation of the external disulfide bond linking the two monomeric units.
The single bond linking the two orthogonal units (C6-C20) is weakly conjugated with a C-C bond length of 1.497 3) Å. Crystals grown by method ii) gave the conformer represented by 13 b.
In this process, the molecules of 1 and 2 were broken into smaller pieces by cleavage of the N=N bond linking the two triazole rings and opening of their triazole rings.
They bind to cellulose through a set of aromatic residues and hydrogen bonding.[ 17] Linking two CBMs together allowed us to systematically adjust the interactions by changing the length of the linkers between the two modules.
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