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We present here syntheses of aminoindolizine, substituted 4H-chromene, and flavanones, and the unexpected formation of a bis-addition product formed after Michael addition, all under mild conditions.
The electrochemical reduction of sulphoxides in aprotic solutions may occur according to a disproportionation-like process with the unexpected formation of sulphinate ion.
The unexpected formation of hydrates in oil and gas pipelines can lead to blockage of the pipelines and critical safety issues.
For R = H, benzoic acids and eventually diaroylhydrazines are obtained; in the special case of o-nitrobenzoylhydrazine, unexpected formation of o-nitrosobenzoic acid is observed.
The X-ray crystal structure of the novel spider-like trispeptide N,N′,N″-tris 2-aminopyridine benzene-1,3,5-tricarboxamide N″-tris 2-aminopyridine benzene-1,3,5-tricarboxamide N″-tris 2-aminopyridine benzene-1,3,5-tricarboxamide N″-tris 2-aminopyridine benzene-1,3,5-tricarboxamide N″-tris 2-aminopyridine benzene-1,3,5-tricarboxamide
The unexpected formation of polymorphs of the antimicrobial compound sulfathiazole is also triggered by impurities or reaction byproducts.
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Rye Neck's unexpected offensive formation, a wishbone instead of their usual I-formation, was effective: Lamont Tucker ran 75 yards for a touchdown on the second play of the game.
Perfectly tuned conditions may thus rapidly change due to unexpected coke formation that will clog the pores of the material and thus strongly affect the cooling efficiency.
Structural analysis of the enzyme revealed an unexpected dimer formation as a consequence of a domain-swapping event involving its N-terminal region.
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