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MCX and MAX SPE fractions were analysed separately to minimize interferences and to determine the fraction of each analyte eluting from the two SPE cartridges.
While for the most dilute systems (n = 20) the two SPE families show similar ionic conductivities in the entire temperature range investigated (273-343 K), for n = 6 and n = 9 they differ significantly; at room temperature, the NaFSI based SPEs show lower ionic conductivities than the NaTFSI based analogues.
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Most of the restatement came from the consolidation of two SPEs.
All plasma samples were split and extracted in duplicate by loading approximately half of the volume onto each of two SPE-columns.
The analytical utility was then studied on four SPE surfaces (carbon, gold, platinum and silver) in two RTILs (one with a pyrrolidinium and one with an imidazolium cation) and linear responses were observed between current and % concentration in the range 10 100% O2.
The intra-day precision of SPE was determined at two concentration levels within the single-laboratory validation, based on five SPE replicates within 1 day, respectively.
Four SPE columns (Strata NH2 (55 μm, 70A) 500 mg, 3 mL) per sample were connected to a vacuum box (Resprep vacuum manifold with 12 ports) and activated with 12 mL MeOH.
Indeed, recoveries and intermediate precision perfectly corresponded with data derived from fetal calf serum deficient MEM samples for BC and all CPs.> -wrap-foot> aThe sample size (n = 15) refers to three SPEs performed on five consecutive days Inter-day precision was based on three extractions per day performed over five consecutive days.
To confirm the concentrations of antiepileptic drugs in the biologically treated waste water, an additional screening with two different SPE cartridges and a lower preconcentration factor was applied.
Apart from that, the results for the biologically treated waste water obtained under the use of the two different SPE cartridges are in good agreement with the previous results (oxcarbazepine excepted).
Two different SPE systems were tested: Strata-X C and PBA.
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