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The turn over number of MV2+ reaches the remarkable high value of 31201/hour, with 72.7 mmol of cyclohexanone dimethyl ketal production in 1 h.
The turn over frequency over SBA-15/γ-aminopropylmethyldimethoxysilane (AEAPMDMS)/Rh catalyst with triphenylphosphine (TPP) ligand prepared by conventional post grafting method was higher than that of the homogeneous catalyst, (Rh(CH3COO 2)2 with TPP.
Immediately DC go up the other end and Pontius just scoops his shot on the turn over.
Marco Cassetti's chipped ball looked one to bring down and lay off but, without breaking stride, Vydra volleyed it on the turn over Kasper Schmeichel.
Playing Sherwood's front side when the weather was at its worst, McDowell made a few clutch swings to take a three-stroke lead at the turn over his playing partner, Bradley.
This could further be substantiated by kinetic studies, wherein parameters such as the Michaelis constant (Km), rate of reaction (Vmax) and the turn over number (Kcat) of the test enzyme for various substrates could be evaluated.
Similar(53)
The turn-over frequency was 1.87 s-1 per cluster for the reduction of 4-np at 35°C.
The turn-over-frequency (TOF) of the optimized responses demonstrated a slightly higher value than the one which was not optimized.
The turn-over-frequency of the catalysts loaded with 8 wt.% of Mo decreased in the order MCM-41 > MCM-48 > SBA-15, while the selectivity slightly increased in the same order.
The turn-over of VAC recruits was most apparent in the trade-centre and roadside villages.
The turn-over rates (kcat) fall in the range 4.95 19.8 min−1, with NADH/DCPIP being the most efficient redox couple.
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