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The calculated results indicate that the strong conjugation is formed in the dyes and the length of conjugate bridge increases gradually with the increased thiophene spacers.
Like all polymers the PMB presents an absorption difference in the visible range function of the polarization potential, it is expressed by the strong conjugation at oxidized state but is weakened with leucoform formation at reduced state.
It is the strong conjugation between metal ion and surrounding nitrogen atoms that prevent the clustering of metal atom.
The close contact of graphene sheets and PANI backbone allows strong conjugation interaction between the two that promotes fast charge transfer resulting in improved electrochemical properties.
Nevertheless, using the lux-monitored conjugation assay with an F- lux plasmid, the same set of LPS mutants showed strong conjugation inhibition (Fig. 6B) suggesting a severe defect in the recipient ability in liquid mating conditions.
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From DFT (density functional theory) calculations, the optimized geometries of organic dyes reflected that the carbazole cores of H-donor dyes were coplanar with the conjugated thiophenes and cyanoacrylic acids, which is essential for strong conjugations across the donor-acceptor units in D1 D4 dyes.
In particular, compared with the adduct of TCNE, the product clicked with TCNQ possessed a stronger D A conjugation and bulkier π spacers.
Using density functional theory (DFT) methods, the nonlinear optical (NLO) properties have been calculated with strong donor-π-conjugation-acceptor configurations.
It has been found that the lower transition energy and higher oscillator strengths cause robustly large amplitudes especially in systems 3a and 4a, which consequently stems in strong donor-π-conjugation-acceptor configuration of these systems.
In Norwegian, there are strong verbs (whose conjugations are completely irregular) and there are weak verbs.
The appearance of the C N stretching band at (1080.49 cm−1) was a strong significance that the conjugation took place in covalent manner through amide linkage.
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