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The department instituted a "no bond" policy for all Sept. 11 detainees.
It was 1965, not long after Ursula Andress filmed that beach scene in the Dr No Bond film.
The NO bond is substantially shorter in comparison with the NO bond in the ZnTPP unit [1.3052(11) Å vs. 1.335(2) Å].
This intrinsic competition between the OC and NO bond homolysis processes has to this point been difficult to probe experimentally.
For most R3 substituents, product ions from homolysis of the OC bond are observed and product ions resulting from cleavage of the NO bond are minor or absent.
Competing homolysis of the alkoxyamine NO bond has been predicted to occur for some substituents leading to production of aminyl and alkoxyl radicals.
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For the oxygen atom transfer the reaction is energetically constraint by the NO bond-breaking step.
The high lability of the S-NO bond makes the study of proteins regulated by S-nitrosylation/denitrosylation a challenging task.
Most studies have focused on already S-nitrosylated proteins and have relied on the lability of the S-NO bond to isolate them.
Exposure to heat, light, and metal ions can cause S-NO bond cleavage; however, d-SSwitch and other approaches to SNO quantitation take precautions against such homolytic degradation.
Connections may span no-bond indicators.
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