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No oxygen-containing compounds were detected at complete conversions.
However, the product distributions changed with time, even at complete conversions, indicating that both catalysts deactivated under the studied conditions.
The method exploits a chemical Knoevenagel Doebner condensation (optimised to give complete conversions in a short reaction time, employing microwave irradiation) and a biocatalytic phenylalanine ammonia lyase mediated hydroamination (for the stereoselective addition of ammonia).
As comparison, mesoporous silica supported Au catalysts was also prepared by straightforward chemical reduction (CR) and impregnation (IM), which behaved poor HCHO catalytic activity with complete conversions at 200 °C and 90 °C respectively.
For the stereoselective hydrogenation of 3-hexyne, Pd GO exhibited an outstanding catalytic performance: at reactant:Pd (S Pd) ratios ⩽ 5000, complete conversions were achieved in 8 15 min and the (Z -alkene stereoselectivities exceeded 98%.
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Similar(54)
A complete conversion was approved by the New York City Planning Commission early this year.
Results confirmed phase separation at complete conversion.
Only complete conversion to their philosophy -- their radical, prehistoric version of Islam -- would be acceptable to them.
Pic-borane and pyridine borane were chosen because of the complete conversion, low toxicity and high stability.
All too often, however, the end result of this approach is the complete conversion of co-ops into conventional businesses.
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