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Following a comprehensive study into the deactivation of a cobalt catalyst under realistic FTS conditions the following intrinsic deactivation mechanisms were identified: (1) sintering of Co active phase, (2) carbon deposition and (3) surface reconstruction.
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Examples include freeze casting [8 10], sponge templating [11, 12], gel casting [13], particle templating [14, 15], whisker sintering [16], robocasting [17], extrusion deposition [18], and slurry foaming [19].
The fabrication method of such dental restoratives is usually as follows: (1) hot pressing of zirconia powder (2) machining of pre-sintered zirconia (3) sintering.
[23] Sintering and densification were observed to result in strength recovery; with sintering time approaching τ s, the strength of single-phase, defect-free melt (glass) was recovered.
Open image in new window Figure 7 Sintering temperature-dependent dielectric constant.
Open image in new window Figure 2 Sintering temperature-dependent apparent density.
Open image in new window Figure 5 Sintering temperature-dependent resistivity.
The results of thermodynamic modeling were then applied in selected B4C sintering experiments.
A permittivity of 19 and initial permeability of 11 was obtained in the ferrite containing 5 wt% B2O3 sintering additive.
The emission of different gas species during B4C sintering, due to the reaction between B2O3 and C, was predicted.
Dense silicon nitride - Molybdenum disilicide (Si3N4-MoSi2) was prepared by spark plasma sintering (SPS) of the Si3N4 and Mo powder mixture with 7 mol% CeO2 sintering additives.
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