Exact(5)
For electrochemical tests in aqueous and organic electrolytes, 6 M KOH and 1 M TEABF4 in anhydrous acetonitrile (AN) solutions were used, respectively.
In propylene carbonate (PC) and acetonitrile (AN) solutions the PPyDBS films swelled and shrunk by oxidation and reduction, respectively, driven by the exchange of anions.
Electrochemical behavior of the dioxygen (O2)/superoxide ion (O2 −) redox couple in acetonitrile (AN) solutions containing indole compounds and no proton acceptor, and their chemiluminescence have been examined using spectroelectrochemical techniques.
Standard potentials for the magnesium and magnesium amalgam electrodes relative to the silver electrode have been determined in dimethylformamide (DMF), propylene carbonate (PC) and acetonitrile (AN) solutions at ambient temperature (295 ± 2K) from emf measurements obtained using both stationary pool and flowing amalgam electrodes.
In AN solutions, in the presence of indole compounds having a substituent at the N-position (e.g. 1-methylindole and 1,2-dimethylindole), these indole compounds did not work as a proton donor to electrogenerated O2 −, and did not affect the redox reaction of the O2/O2 − couple.
Similar(55)
Clear redox peaks of Co phen 33+ were observed both in an aqueous and AN solutions.
The absorption spectra of the oxidation products of ortho- or meta-toluidine or anisidine in acetonitrile (AN) were observed using a stopped-flow technique by mixing with AN solutions of the tris p-bromophenyl)amine (tris p-bromophenylamine
It was found that the renewed iron electrode in LiClO4 or KBF4 solutions in a certain potential region behaves in the first approximation as an ideally polarizable electrode (with the exception of DMSO and AN solutions).
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